| 反式-9,10-二氢-9,10-二苄基-9,10-菲二醇的合成与表征 |
| |
| 引用本文： | 潘燕琼,洪茵,朱峰.反式-9,10-二氢-9,10-二苄基-9,10-菲二醇的合成与表征[J].佛山科学技术学院学报(自然科学版),2005,23(3):51-53. |
| |
| 作者姓名： | 潘燕琼 洪茵 朱峰 |
| |
| 作者单位： | 佛山科学技术学院,化学与化工系,广东,佛山,528000 |
| |
| 摘 要： | 以菲醌为原料合成了标题化合物,通过IR和1H NMR对其结构进行了表征.氢谱分析表明,亚甲基二氢核构成了AB二级谱自旋体系,这主要是由于孤立亚甲基的2个氢是化学不等价造成的.通过Chem3D程序模拟得到了标题化合物的能量最优化立体结构.
|
| 关 键 词： | 反式-9 10-二氢-9 10-二苄基-9 10-菲二醇 合成 波谱表征 |
| 文章编号： | 1008-0171（2005）03-0051-03 |
| 收稿时间： | 2005-05-09 |
| 修稿时间： | 2005年5月9日 |
Synthesis and spectral characterization of trans-9, 10-dibenzyl- 9,10-dihydro- 9,10-phenanthrenediol |
| |
| PAN Yan-qiong,HONG Yin,ZHU Feng.Synthesis and spectral characterization of trans-9, 10-dibenzyl- 9,10-dihydro- 9,10-phenanthrenediol[J].Journal of Foshan University(Natural Science Edition),2005,23(3):51-53. |
| |
| Authors: | PAN Yan-qiong HONG Yin ZHU Feng |
| |
| Abstract: | The title compound was synthesized with phenanthrenequinone as starting material and was characterized by IR and 1H NMR spectra. 1H NMR spectra analysis showed that the signals of two hydrogen nuclei of methene formed AB spin system in second-order spectra because of its chemical unequivalence. The mini-energy stereosturcture of the title compound was obtained by Chem3D program. |
| |
| Keywords: | trans-9 10-dibenzyl-9 10-dihydro-9 10-phenanthrenediol synthesis spectral characterization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
