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Short communication: Stille coupling reactions of functionalized triorganotin halides |
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| Authors: | Christina M Thiele Terence N Mitchell |
| Abstract: | Convenient conditions for the Stille coupling of halide‐bearing triorganotin compounds, which do not normally react under typical Stille reaction conditions, are presented. The coupling of vinylstannanes with allyl bromide using palladium(II) catalysis is accomplished under fluoride assistance to give the substituted 2,5‐hexadien‐1‐ols in Z‐configuration. Copyright © 2004 John Wiley & Sons, Ltd. |
| Keywords: | Stille coupling triorganotin halides allylic alcohols fluoride assistance |
