Compatibility of polysaccharide/maleic copolymer blends. IV. Thermal behavior of hydroxypropyl cellulose‐containing blends |
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Authors: | Gina‐Gabriela Bumbu Cornelia Vasile Maria Cristina Popescu Hristea Darie Gabrielle Charlotte Chianu Gheorghe Singurel Adrian Carpov |
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Affiliation: | Gina‐Gabriela Bumbu,Cornelia Vasile,Maria Cristina Popescu,Hristea Darie,Gabrielle Charlotte Chi?anu,Gheorghe Singurel,Adrian Carpov |
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Abstract: | The compatibility of the hydroxypropyl cellulose (HPC) with maleic acid–vinyl acetate copolymer in the solid state was studied by thermogravimetry, thermo‐optical analysis, differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and optical microscopy. It was established that physical interactions are prevalent in blends with a high content of HPC, whereas chemical interactions predominate in blends with a medium and low content of HPC. By increasing the temperature, the thermochemical reactions are favored. Thermal properties are dependent on the mixing ratio of the components. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2585–2597, 2003 |
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Keywords: | blends compatibility thermal properties morphology |
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