Estimation of the effective conjugation length of oligo-p-phenylenes from specific refractive index increments of solutions |
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Authors: | Jiří Dostál Lubomír Šimek Miloslav Bohdanecký |
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Affiliation: | (1) Faculty of Technology, Technical University, 762 72 Zlín, Czech Republic, XX;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic, XX |
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Abstract: | Summary An unusually strong molecular weight dependence of the specific refractive index increment which has been reported for solutions of oligomers (M < 103) of p-2-methyl phenylene is attributed to the exaltation of polarizability of phenylene units. The saturation length is estimated to be l s≅ 6 phenylene units. Received: 3 November 1997/Revised version: 20 April 1998/Accepted: 22 April 1998 |
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