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纳米CaCO3填充新型聚烯烃弹性体POE的力学、流变性能研究
引用本文:熊忠,陈骁,韩高亮,王晓林,王淑英,吴其晔.纳米CaCO3填充新型聚烯烃弹性体POE的力学、流变性能研究[J].弹性体,2005,15(2):14-18.
作者姓名:熊忠  陈骁  韩高亮  王晓林  王淑英  吴其晔
作者单位:青岛科技大学高分子科学与工程学院,山东,青岛,266042
基金项目:国家自然科学基金资助项目(50273016)
摘    要:用纳米CaCO3填充新型聚烯烃弹性体POE,研究了填充体系的力学性能和流变性能随纳米CaCO3含量变化的规律。发现纳米CaCO3填充量增加至40份时,体系仍具有良好的力学强度,流动性变化很小。从流动曲线上发现了一些反常现象,即随纳米CaCO3含量增加,体系粘度降低,粘切敏感性降低,非牛顿性减弱,推断这种反常的现象应该与纳米CaCO3纳米级的尺寸和立方体形的结构有关。

关 键 词:纳米CaCO3  聚烯烃弹性体  POE  性能研究  CaCO3含量  含量变化  流变性能  力学性能  填充体系  力学强度  反常现象  流动曲线  粘度降低  非牛顿性  填充量  流动性  敏感性  纳米级
文章编号:1005-3174(2005)02-0014-05
修稿时间:2004年11月22

Studies on mechanical and rheological properties of new-type polyolefin elastomer POE filled with nano-CaCO3
XIONG Zhong,CHEN Xiao,HAN Gao-liang,WANG Xiao-lin,WANG Shu-ying,WU Qi-ye.Studies on mechanical and rheological properties of new-type polyolefin elastomer POE filled with nano-CaCO3[J].China Elastomerics,2005,15(2):14-18.
Authors:XIONG Zhong  CHEN Xiao  HAN Gao-liang  WANG Xiao-lin  WANG Shu-ying  WU Qi-ye
Abstract:Nano-calcium carbonate was filled into new-type polyolefin elastomer,and the influences of nano-calcium carbonate content on the mechanical properties and rheological behavior of the system were investigated.The results showed that when the content of nano-CaCO_3 reached 40 phr,the system kept having good mechanical properties,and the rheological behavior changed little.From the rheological curve,some abnormal phenomena were found,which indicated that with the increasing of nano-CaCO_3 content,the viscosity of POE/nano-CaCO_3 system decreased,the viscosity-shear sensitivity decreased,and non-Newton character weakened.It was concluded that the phenomena were related with the nano-meter dimension and cuboid shape of nano-CaCO_3.
Keywords:nano-calcium carbonate  polyolefin elastomer  mechanical property  rheological property
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