| 新型稀土配合物Tb(bza)3(dpe)(H2O)3的表征及热分解动力学性质 |
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| 引用本文： | 侯向阳,王潇,李东升,付峰,王记江,任宜霞.新型稀土配合物Tb(bza)3(dpe)(H2O)3的表征及热分解动力学性质[J].化学与生物工程,2009,26(6):27-31. |
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| 作者姓名： | 侯向阳 王潇 李东升 付峰 王记江 任宜霞 |
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| 作者单位： | 1. 延安大学化学与化工学院,陕西省化学反应工程重点实验室,陕西,延安,716000
2. 延安大学化学与化工学院,陕西省化学反应工程重点实验室,陕西,延安,716000;三峡大学机械与材料学院,湖北,宜昌,443002 |
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| 基金项目： | 国家自然科学基金，教育部重点科研项目，河北省自然科学基金，第二届延安大学大学生科技创新训练计划，陕西省教育厅资助项目和重点实验室基金 |
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| 摘 要： | 合成了新型稀土固态配合物Tb（bza）3（dpe）（H2O）3（Hbza=Benzoic acid,dpe=1,2-Di-（4-pyridyl）-ethylen]。通过元素分析和化学分析确定了配合物的组成,采用红外光谱等技术对配合物进行了表征,研究了配合物的荧光性能,用TG-DTG法研究了配合物的热分解行为,用非模型等转化率法研究了配合物热分解脱水过程的动力学,获得其表观活化能、指前因子数值范围、最概然机理函数和模型函数。
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| 关 键 词： | 铽 表征 荧光性能 热分解动力学 |
Characterization and Thermal Decomposition Kinetics Properties of A Novel Rare Earth Complex Tb(bza)3(dpe)(H2O)3 |
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| HOU Xiang-yang,WANG Xiao,LI Dong-sheng,FU Feng,WANG Ji-jiang,REN Yi-xia.Characterization and Thermal Decomposition Kinetics Properties of A Novel Rare Earth Complex Tb(bza)3(dpe)(H2O)3[J].Chemistry & Bioengineering,2009,26(6):27-31. |
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| Authors: | HOU Xiang-yang WANG Xiao LI Dong-sheng FU Feng WANG Ji-jiang REN Yi-xia |
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| Abstract: | The novel rare earth complex Tb(bza)3(dpe)(H2O)3 Hbza= benzoic acid,dpe = 1,2-di-(4-pyridyl)-ethylen] was self-assembled under hydrothermal conditions.The composition of the complex was confirmed by means of chemical and elemental analyses,which was characterized by means of FTIR method.Fluorescence properties had also been investigated.The thermal decomposition was investigated by TG-DTG. Furthermore,the decomposition process was studied by model-free isoconversional method in order to obtain the apparent... |
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| Keywords: | terbium characterization fluorescence property thermal decomposition kinetics |
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