| 5，11-二乙基吲哚[3，2-b]咔唑的合成及光谱特性 |
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| 引用本文： | 刘世洋,费学宁,谷迎春,李玲. 5，11-二乙基吲哚[3，2-b]咔唑的合成及光谱特性[J]. 天津城市建设学院学报, 2013, 0(4): 280-283 |
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| 作者姓名： | 刘世洋 费学宁 谷迎春 李玲 |
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| 作者单位： | 天津城建大学理学院,天津300384 |
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| 基金项目： | 国家自然科学基金（51178289）;天津市高等学校科技发展基金计划项目（20110509） |
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| 摘 要： | 以苯肼为原料，与1，4-环己二酮反应，制得环己胺-1，4-二酮一二苯腙，再在硫酸、醋酸强酸性环境下闭环制得吲哚[3，2-b]咔唑，经N-烷基化反应制得乙基取代基的吲哚[3，2-b]咔唑衍生物．本文合成方法使其产率由参考文献的64％提升到80％，其结构经’HNMR表征，并初步研究了该化合物的光谱性质．
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| 关 键 词： | 苯肼 吲哚[3,2-b]咔唑 N一烷基化反应 |
The Modified Synthesis and Properties Study of 5,11 -Diethyl-5,11- Dihydroindolo [3,2 -b] Carbazole |
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| LIU Shi-yang,FEI Xue-ning,GU Ying-chun,LI Ling. The Modified Synthesis and Properties Study of 5,11 -Diethyl-5,11- Dihydroindolo [3,2 -b] Carbazole[J]. Journal of Tianjin Institute of Urban Construction, 2013, 0(4): 280-283 |
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| Authors: | LIU Shi-yang FEI Xue-ning GU Ying-chun LI Ling |
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| Affiliation: | (School of Science, Tianjin Chengjian University, Tianjin 300384, China) |
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| Abstract: | Using phenylhydrazine and 1,4-cyclohexanedione as raw materials, cyclohexane-l,4-dione bis （phenylhydra- zone） was synthesized. Then, in the presence of sulfuric acid and acetic acid, indole [3,2-b] carbazole was obtained through cyclization. Finally, 5,11-Diethyl-5,11 -dihydroindolo[3,2-b] carbazole was synthesized through N-alkylation reaction. This method increased the reaction yield from 64% in the reference to 80%. The structures were characterized by lH NMR and the fluorescent spectra were studied. |
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| Keywords: | phenylhydrazine indole [3,2-b] carbazole~ N-alkylation reaction |
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