Photocatalytic degradation of 4-nitroaniline using solar and artificial UV radiation |
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Authors: | Satyen Gautam Sanjay P. Kamble Sudhir B. Sawant Vishwas G. Pangarkar |
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Affiliation: | Chemical Engineering Department, Institute of Chemical Technology, Mumbai University Matunga, Mumbai 400019, India |
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Abstract: | The photocatalytic degradation (PCD) of 4-nitroaniline was studied in the presence of TiO2 suspensions in a batch and continuous annular reactor. Artificial and solar radiation was employed as sources of UV radiation. The effect of catalyst loading, pH, presence of anions and initial concentration on the rate of photocatalytic degradation was investigated. p-Aminophenol, p-benzoquinone and hydroquinone were identified as the intermediates during the degradation process. A kinetic expression for PCD of 4-NA is provided. |
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Keywords: | Nitroaniline Photocatalysis TiO2 Kinetics |
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