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Activity measurement of the constituents in molten Fe–B and Fe–B–C alloys
Authors:Takahiro Miki  Kenjirou Tsujita  Shiro Ban-Ya  Mitsutaka Hino
Affiliation:

aDepartment of Metallurgy, Graduate School of Engineering, Tohoku University, Aoba-yama 6-6-02, Sendai, 980-8579, Japan

Abstract:The distribution ratios of Fe and B between molten Fe–B alloy and molten Ag were measured at temperatures between 1573 and 1923 K. Also, distribution ratios of Fe and B between molten Fe–B–Csatd. alloys and molten Ag were measured at 1873 K. It was found that the excess Gibbs free energy of mixing in molten Fe–B and Fe–B–C alloys can be expressed by utilizing the Redlich–Kister polynomial. The activity curves of the elements in molten Fe–B alloy and Fe–B–C alloy were estimated.
Keywords:Activity  Equilibrium  Excess Gibbs free energy  Redlich–Kister polynomial
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