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WO3-Assisted Synergetic Effect Catalyzes Efficient and CO-Tolerant Hydrogen Oxidation for PEMFCs
Authors:Han Tian  Xu Yu  Weimin Huang  Ziwei Chang  Fenglai Pei  Jiangdong Zhou  Ningning Dai  Ge Meng  Chang Chen  Xiangzhi Cui  Jianlin Shi
Affiliation:1. State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050 China;2. State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050 China

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049 China;3. State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050 China

School of Physical Science and Technology, Shanghai Tech University, Shanghai, 201210 China;4. Shanghai Motor Vehicle Inspection Certification & Tech Innovation Center Co., Ltd., Shanghai, 201805 China;5. Nantong Bing Energy Co., Ltd., Rugao, 226500 China

Abstract:Developing anode catalysts with substantially enhanced activity for hydrogen oxidation reaction (HOR) and CO tolerance performance is of great importance for the commercial applications of proton exchange membrane fuel cells (PEMFCs). Herein, an excellent CO-tolerant catalyst (Pd-WO3/C) has been fabricated by loading Pd nanoparticles on WO3 via an immersion-reduction route. A remarkably high power density of 1.33 W cm−2 at 80 °C is obtained by using the optimized 3Pd-WO3/C as the anode catalyst of PEMFCs, and the moderately reduced power density (73% remained) in CO/H2 mixed gas can quickly recover after removal of CO-contamination from hydrogen fuel, which is not possible by using Pt/C or Pd/C as anode catalyst. The prominent HOR activity of 3Pd-WO3/C is attributed to the optimized interfacial electron interaction, in which the activated H* adsorbed on Pd species can be effectively transferred to WO3 species through hydrogen spillover effect and then oxidized through the H species insert/output effect during the formation of HxWO3 in acid electrolyte. More importantly, a novel synergetic catalytic mechanism about excellent CO tolerance is proposed, in which Pd and WO3 respectively absorbs/activates CO and H2O, thus achieving the CO electrooxidation and re-exposure of Pd active sites for CO-tolerant HOR.
Keywords:CO tolerance  fuel cells  hydrogen oxidation reaction  hydrogen spillover effect  tungsten oxide
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