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平行沟槽织构对TB6钛合金表面润湿性、摩擦学性能和耐腐蚀性的改善
引用本文:郭嘉梁,王芳,刘俊杰,刘玉怀.平行沟槽织构对TB6钛合金表面润湿性、摩擦学性能和耐腐蚀性的改善[J].稀有金属材料与工程,2024,53(3):617-624.
作者姓名:郭嘉梁  王芳  刘俊杰  刘玉怀
作者单位:郑州大学 电气与信息工程学院 电子材料与系统国际联合研究中心 河南省电子材料与系统国际联合实验室,河南 郑州 450001,郑州大学 电气与信息工程学院 电子材料与系统国际联合研究中心 河南省电子材料与系统国际联合实验室,河南 郑州 450001;郑州大学 智能传感研究院,河南 郑州 450001;郑州大学 产业技术研究院有限公司,河南 郑州 450001;郑州唯独电子科技有限公司,河南 郑州 450001,北方民族大学 电气与信息工程学院,宁夏 银川 750001,郑州大学 电气与信息工程学院 电子材料与系统国际联合研究中心 河南省电子材料与系统国际联合实验室,河南 郑州 450001;郑州大学 智能传感研究院,河南 郑州 450001;郑州大学 产业技术研究院有限公司,河南 郑州 450001;郑州唯独电子科技有限公司,河南 郑州 450001
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目),国家重点研发计划,河南省国际科技合作重点项目 ,宁波市“科技创新2025”重大专项, 智慧郑州·1125聚才计划
摘    要:提出了一种快速制备具有超疏水性、耐磨性和耐腐蚀性的Ti-10V-2Fe-3Al (TB6)钛合金表面的方法。通过纳秒激光器对抛光的钛合金进行精确烧蚀,构筑了具有平行微沟槽阵列特征的织构表面。随后,利用紫外线灯照射和十八烷基三氯硅烷溶液浸渍进行化学改性,进一步增强了表面的疏水性。从表面形态和化学组分的角度分析了微沟槽间隔对织构表面润湿性的影响。结果表明,在干滑动、水润滑和油润滑条件下,所制备的超疏水表面相较于原始亲水表面,平均摩擦系数分别降低了34%、56%和59%。此外,分析了相关摩擦系数变化的机理。通过动电位极化测试验证,所制备的超疏水表面展现出优异的耐腐蚀性,为钛合金基体提供了有效的长期保护。

关 键 词:激光织构  钛合金  超疏水性  摩擦学性能  耐腐蚀性
收稿时间:2023/5/6 0:00:00
修稿时间:2023/6/30 0:00:00

Parallel Groove-Textured TB6 Titanium Alloy Surfaces for Improving Wettability, Tribological Properties and Corrosion Resistance
Guo Jialiang,Wang Fang,J Liou Juin and Liu Yuhuai.Parallel Groove-Textured TB6 Titanium Alloy Surfaces for Improving Wettability, Tribological Properties and Corrosion Resistance[J].Rare Metal Materials and Engineering,2024,53(3):617-624.
Authors:Guo Jialiang  Wang Fang  J Liou Juin and Liu Yuhuai
Affiliation:International Joint-Laboratory of Electronic Materials and Systems of Henan Province, National Center for International Joint Research of Electronic Materials and Systems, School of Electrical and Information Engineering, Zhengzhou University, Zhengzhou 450001, China,International Joint-Laboratory of Electronic Materials and Systems of Henan Province, National Center for International Joint Research of Electronic Materials and Systems, School of Electrical and Information Engineering, Zhengzhou University, Zhengzhou 450001, China;Institute of Intelligence Sensing, Zhengzhou University, Zhengzhou 450001, China;Research Institute of Industrial Technology Co., Ltd, Zhengzhou University, Zhengzhou 450001, China;Zhengzhou Way Do Electronics Co., Ltd, Zhengzhou 450001, China,School of Electrical and Information Engineering, North Minzu University, Yinchuan 750001, China,International Joint-Laboratory of Electronic Materials and Systems of Henan Province, National Center for International Joint Research of Electronic Materials and Systems, School of Electrical and Information Engineering, Zhengzhou University, Zhengzhou 450001, China;Institute of Intelligence Sensing, Zhengzhou University, Zhengzhou 450001, China;Research Institute of Industrial Technology Co., Ltd, Zhengzhou University, Zhengzhou 450001, China;Zhengzhou Way Do Electronics Co., Ltd, Zhengzhou 450001, China
Abstract:We proposed an efficient method to fabricate superhydrophobic, wear and corrosion resistant groove-textured surfaces based on TB6 (Ti-10V-2Fe-3Al) titanium alloy substrates. The smooth surface of the titanium alloy was ablated using a nanosecond laser to create a surface with a parallel groove pattern. In order to further improve the surface hydrophobicity, the laser treated surface was irradiated by an ultraviolet lamp for 1 h and subsequently immersed in a 3wt% octadecyltrichlorosilane solution for 2 h for chemical modification. The wettability of the groove-textured surfaces with varying groove spacing was investigated by analyzing surface morphology and chemical composition. Results show that the average coefficient of friction (COF) of the superhydrophobic surface is reduced by 34%, 56%, and 59% compared with that of the original hydrophilic surface under dry, water, and oil lubrication conditions, respectively. The mechanism variation of the CoF was also discussed. Potentiokinetic polarization testing demonstrates that the prepared superhydrophobic surface provides corrosion protection for the titanium alloy substrate.
Keywords:laser texturing  titanium alloy  superhydrophobicity  tribological properties  corrosion resistance
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