金属有机骨架HKUST-1及其衍生材料在催化中的应用进展

金属有机骨架材料(MOFs)作为异相催化剂受到了日益广泛的关注。在众多经典MOFs结构中，HKUST-1及其衍生材料是研究最多的类型之一。HKUST-1具有原料简单、易于合成、结构稳定、孔隙率高等多种优点，在异相催化领域中具有广阔的应用前景。已有多种HKUST-1相关材料被用作催化剂，包括HKUST-1本身、缺陷型结构、负载活性客体分子的复合型材料以及HKUST-1衍生的多孔碳纳米材料等。本文围绕HKUST-1作为催化剂的结构设计以及在不同催化反应中的应用展开总结与介绍，以期为相关MOFs材料的设计和催化研究提供一定参考。

Catalytic application of metal-organic framework HKUST-1 and its derivatives

Metal-organic frameworks (MOFs) have received increasing attention as heterogeneous catalysts. Among the many classical MOFs structures, HKUST-1 and its derivatives are one of the most studied types. Taking the advantages of simple raw materials, easy synthesis, stable structure and high porosity, there is broad development prospect for the application of HKUST-1 in heterogeneous catalysis. A variety of materials related to HKUST-1 have been used as catalysts, including HKUST-1 itself, defective structures, composite materials with active guest molecules, and HKUST-1-derived porous carbon nanomaterials. This paper summarizes and introduces the structural design of HKUST-1 as a catalyst and its application in different catalytic reactions, aiming to provide some reference for the design and catalytic research of MOF-related materials.