| 草甘膦丙烯酸树脂的合成及其对微生物的抑制毒性研究 |
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| 引用本文： | 江学志,黄从树,黄志雄,任润桃,王晶晶. 草甘膦丙烯酸树脂的合成及其对微生物的抑制毒性研究[J]. 涂料工业, 2012, 42(3): 55-58 |
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| 作者姓名： | 江学志 黄从树 黄志雄 任润桃 王晶晶 |
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| 作者单位： | 1. 武汉理工大学,武汉,430070
2. 中国船舶重工集团公司第七二五研究所厦门分部,福建厦门361002;海洋腐蚀与防护重点实验室,福建厦门361002 |
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| 基金项目： | 国家重点基础研究发展计划(973计划) |
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| 摘 要： | 采用丙烯酰氯对草甘膦进行化学改性,使其接枝活性双键,合成丙烯酰草甘膦,并用FT-IR、1H-NMR和13C-NMR等分析手段表征丙烯酰草甘膦的化学结构。丙烯酰草甘膦用乙二醇酯化后与其他丙烯酸酯类单体共聚,制备草甘膦丙烯酸树脂。微生物抑制毒性试验表明草甘膦丙烯酸树脂薄膜的水解产物对藤壶金星幼体具有良好的杀生作用,为将该树脂应用于新型环境友好型防污涂料奠定了基础。
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| 关 键 词： | 草甘膦 化学改性 草甘膦丙烯酸树脂 抑制毒性 |
Study on Synthesis of Glyphosate-Acrylate Resin and Its Inhibition Toxicity on Microbes |
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| Jiang Xuezhi , Huang Congshu , Huang Zhixiong , Ren Runtao , Wang Jingjing. Study on Synthesis of Glyphosate-Acrylate Resin and Its Inhibition Toxicity on Microbes[J]. Paint & Coatings Industry, 2012, 42(3): 55-58 |
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| Authors: | Jiang Xuezhi Huang Congshu Huang Zhixiong Ren Runtao Wang Jingjing |
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| Affiliation: | 2,3(1.Wuhan University of Technology,Wuhan 430070,China; 2.Xiamen Branch of Luoyang Ship Material Institute,Xiamen,Fujian 361002,China; 3.Science and Technology on Marine Corrosion and Protection Laboratory,Xiamen,Fujian 361002,China) |
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| Abstract: | Glyphosate was chemically modified with acryloyl chloride,which was then grafted with double bonds to prepare N-acryloyl-glyphosate.The structure of N-acryloyl-glyphosate was characterized by FT-IR,1H-NMR and 13C-NMR.The N-acrylogl-glyphosate was esterified with glycol and then copolymerized with other acrylic monomers to prepare glyphosate-acrylate resin.The result of inhibition toxicity test for barnacle venus larvae microbial showed that the insecticide effect of glyphosate-acrylate resin was excellent,which would be used in environment friendly antifouling paint. |
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| Keywords: | glyphosate chemically modification glyphosate-acrylate resin inhibition toxicity |
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