N-Cyanomethyl-β-chloroamines: a convenient source of aziridinium ions |
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| Authors: | François Couty Gwilherm Evano Damien Prim |
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| Affiliation: | SIRCOB, UMR CNRS 8086, Université de Versailles, 45, avenue des Etats-Unis, 78035 Versailles Cédex, France |
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| Abstract: | N-Cyanomethyl-β-chloroamines smoothly react with a range of alcohols or amines to give regio- and stereoselectively 1,2-aminoethers or 1,2-diamines. The reaction proceeds through the formation of an intermediate aziridinium ion. The N-cyanomethyl group can then be cleaved easily. |
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| Keywords: | 1 2-Aminoethers 1 2-Diamines |
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