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基于固相转化机理合成五元环沸石的新技术
引用本文:张瑛,窦涛,鲍晓军,李玉平,李晓峰. 基于固相转化机理合成五元环沸石的新技术[J]. 中国化学工程学报, 2003, 11(6): 656-659
作者姓名:张瑛  窦涛  鲍晓军  李玉平  李晓峰
作者单位:[1]TheKeyLaboratoryofCatalysis,ChinaNationalPetroleumCo.,UniversityofPetroleum,Beijing102249,China [3]InstituteofSpecialChemicals,TaiyuanUniversityofTechnology,Taiyuan030024,China
基金项目:Supported by the National Natural Science Foundation of China (No.20173039) and by China National Petroleum Corporation (No.2002B50501)
摘    要:A novel technology of preparing zeoliltes based on solid-solid mass transformation mechanism is developed for the first time. By employing this technology, three different types of highly crystallized pentasil zeolites,ZSM-35 (FER-type), Silicalite-l(MFI-type) and Mordenite(MOR-type), are successfully synthesized in the solid system. In terms of commercial production, the technology‘could simplify synthesis procedure and make the continuous production of zeolites possible, so as to improve the productivity. Additionally, it is environmentally friendly because the crystallization occurs in solid phase where there exists no pollution caused by waste liquid. Therefore, this technique provides us with a new indusr, rial process for the clean and continuous production of zeolites.The characteristics in synthesis chemistry and the crystallization mechanism involved in the technology are also discussed.

关 键 词:固相转化理论 五元环沸石 化学合成 模板 ZSM-35 发光沸石
修稿时间: 

A Novel Technology for Synthesizing Pentasil Zeolites Based on Solid-Solid Mass Transformation Mechanism
ZHANG Ying,DOU Tao,Bao Xiaojun,LI Yuping,LI Xiaofeng. A Novel Technology for Synthesizing Pentasil Zeolites Based on Solid-Solid Mass Transformation Mechanism[J]. Chinese Journal of Chemical Engineering, 2003, 11(6): 656-659
Authors:ZHANG Ying  DOU Tao  Bao Xiaojun  LI Yuping  LI Xiaofeng
Affiliation:The Key Laboratory of Catalysis, China National Petroleum Co., University of Petroleum, Beijing,102249, China Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan, 030024,China
Abstract:A novel technology of preparing zeolites based on solid-solid mass transformation mechanism is developed for the first time. By employing this technology, three different types of highly crystallized pentasil zeolites, ZSM-35 (FER-type), Silicalite-1(MFI-type) and Mordenite(MOR-type), are successfully synthesized in the solid system. In terms of commercial production, the technology-could simplify synthesis procedure and make the continuous production of zeolites possible, so as to improve the productivity. Additionally, it is environmentally friendly because the crystallization occurs in solid phase where there exists no pollution caused by waste liquid. Therefore, this technique provides us with a new industrial process for the clean and continuous production of zeolites. The characteristics in synthesis chemistry and the crystallization mechanism involved in the technology are also discussed.
Keywords:pentasil zeolites   synthesis   solid phase transformation   template
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