| 聚合钼邻巯基苯酚配合物的合成及性质 |
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| 引用本文： | 王修建,梁宏,曾建强,翟应离,王秋莹. 聚合钼邻巯基苯酚配合物的合成及性质[J]. 广西科学, 1995, 2(1): 28-29,33 |
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| 作者姓名： | 王修建 梁宏 曾建强 翟应离 王秋莹 |
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| 作者单位： | 广西师范大学化学系，兰州大学化学系 |
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| 摘 要： | 以（ｎ－Ｂｕ４Ｎ）４［Ｍｏ８Ｏ２６］为原料，邻巯基苯酚为配体，在乙腈中合成了混合价聚合钼配合物。通过元素分析、红外光谱、＾１ＨＮＭＲ谱、电子光谱、ＥＳＰ谱、差热－热重分析，对此配合物进行了表征，并提出可能结构。
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| 关 键 词： | 聚合钼配合物 钼硫键 巯基苯酚 |
| 收稿时间： | 1994-04-08 |
| 修稿时间： | 1994-08-03 |
Synthesis and Spectroscopic Properties of Polymolybdenum o-mercaptophenol Complex |
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| Wang Xiujian,Liang Hong,Zeng Jianqiang,Zhai Yingli and Wang Qiuying. Synthesis and Spectroscopic Properties of Polymolybdenum o-mercaptophenol Complex[J]. Guangxi Sciences, 1995, 2(1): 28-29,33 |
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| Authors: | Wang Xiujian Liang Hong Zeng Jianqiang Zhai Yingli Wang Qiuying |
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| Affiliation: | Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004,Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004,Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004,Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004 and Department of chemistry, Guangxi Normal University, Sanlidian, Guilin, Guangxi, 541004 |
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| Abstract: | The polymolybdenum complex (n-Bu4N)4 [Mo5O10 ( )4 () )2] was synthe sized in acetonitrile with o-mercaptophenol as the ligand and (n-Bu4N)4 [Mo8O26] as the parent. The properties of the complex were characterized by elemental analysis, molar conductivity, electronic spectra, infrared spectra, 1HNMR spectra and TG-DTA. The most possible structure was proposed on the basis of spectra data. |
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| Keywords: | polymolybdenum complex molybdenum-sulfur bond o-mercaptophenol |
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