Hypervalent Iodine(III)‐Catalyzed Balz–Schiemann Fluorination under Mild Conditions |
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| Authors: | Bo Xing Dr Chuanfa Ni Prof?Dr Jinbo Hu |
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| Affiliation: | Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai, China |
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| Abstract: | An unprecedented hypervalent iodine(III) catalyzed Balz–Schiemann reaction is described. In the presence of a hypervalent iodine compound, the fluorination reaction proceeds under mild conditions (25–60 °C), and features a wide substrate scope and good functional‐group compatibility. |
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| Keywords: | aryl fluorides Balz– Schiemann reaction diazonium salts fluorination iodine |
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