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Reversible Response of Luminescent Terbium(III)–Nanocellulose Hydrogels to Anions for Latent Fingerprint Detection and Encryption
Authors:Jun Hai  Tianrong Li  Junxia Su  Prof Weisheng Liu  Yanmin Ju  Prof Baodui Wang  Prof Yanglong Hou
Affiliation:1. State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Lanzhou University, Gansu, Lanzhou, China;2. Beijing Key Laboratory for Magnetoelectric Materials and Devices (BKLMMD), Beijing Innovation Center for Engineering Science and Advanced Technology (BIC-ESAT), Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, China
Abstract:Fingerprint fluorescence imaging has become one of the most prominent technologies in the field of forensic medicine, but it seldom considers the security protection of detection information, which is of great importance in modern society. Herein we demonstrate that luminescent TbIII–carboxymethyl cellulose (CMC) complex binding aptamer hydrogels that are reversibly responsive to ClO?/SCN? can be used for the selective detection, protection, and storage of fingerprint information. The imaging information of the fingerprint can be quenched and recovered by ClO?/SCN? regulation, respectively, resulting in reversible on/off conversion of the luminescence signals for the encryption and decryption of multiple levels of information. The present study opens new avenues for multilevel imaging, data recording, and security protection of fingerprint information with tunable fluorescent hydrogels.
Keywords:data security  lanthanides  latent fingerprint detection  materials science  nanocellulose hydrogels
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