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电位滴定分析方法在地质样品主量元素检测中的应用
引用本文:栾日坚,张 珂,马 明,张 姝,李艳香.电位滴定分析方法在地质样品主量元素检测中的应用[J].中国无机分析化学,2017,7(1):22-27.
作者姓名:栾日坚  张 珂  马 明  张 姝  李艳香
作者单位:中国冶金地质总局山东局测试中心,山东省地质分析测试工程实验室,济南270000
基金项目:公益性行业科研专项(20141078);山东省地质勘查项目(鲁勘字(2013)155号)资助
摘    要:对电化学分析法与电位滴定法的发展进行了简要介绍。电位滴定法是将电位分析与传统滴定法进行结合的新型分析方法,其反应类型包括酸碱滴定、沉淀滴定、氧化还原滴定与络合滴定,因其仪器操作简单,终点判断更加明确且节省人力的特点而得到广泛关注,因此就近年来电位滴定在地质样品中主量元素检测的应用进行了总结,分别对石灰石、白云石、硅酸盐、铬矿石、铁矿石、锰矿石、铜矿石与水等地质样品的电位滴定检测方法进行了阐述,电位滴定的应用将随着技术发展得以提升。

关 键 词:电位滴定  地质样品分析  进展
收稿时间:2016/5/30 0:00:00
修稿时间:2016/10/10 0:00:00

Application of Potentiometric Titration for Determination of Major Elements in Geological Samples
LUAN Rijian,ZHANG Ke,MA Ming,ZHANG Shu and LI Yanxiang.Application of Potentiometric Titration for Determination of Major Elements in Geological Samples[J].Chinese Journal of Inorganic Analytical Chemistry,2017,7(1):22-27.
Authors:LUAN Rijian  ZHANG Ke  MA Ming  ZHANG Shu and LI Yanxiang
Affiliation:The Testing Center of Shandong Bureau of China Metallurgical geology Bureau, Shandong Geological Analysis Project Laboratory, Jinan,Shandong 270000,China,The Testing Center of Shandong Bureau of China Metallurgical geology Bureau, Shandong Geological Analysis Project Laboratory, Jinan,Shandong 270000,China,The Testing Center of Shandong Bureau of China Metallurgical geology Bureau, Shandong Geological Analysis Project Laboratory, Jinan,Shandong 270000,China,The Testing Center of Shandong Bureau of China Metallurgical geology Bureau, Shandong Geological Analysis Project Laboratory, Jinan,Shandong 270000,China and The Testing Center of Shandong Bureau of China Metallurgical geology Bureau, Shandong Geological Analysis Project Laboratory, Jinan,Shandong 270000,China
Abstract:The developments of electrochemical analysis and potentiometric titration method were briefly introduced in this article. Potentiometric titration is a new analytical method which combines potentiometric analysis with traditional volumetric method, and it includes four reaction types, namely acid-base titration, precipitation titration, redox titration and complex metric titration. Potentiometric titration has gained wide attention for its easy operation, clear titration terminal point and man power saving. The application of potentiometric titration for the detection of major elements in geological samples were summarized. How potentiometric titration method was used in analyzing the geological samples, including limestone, dolomite, silicate, chrome ore, iron ore, manganese ore, copper ore and water, were described. The application of potentiometric titration will increase with continuous technology development.
Keywords:potentiometric titration  analysis of geological samples  progress
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