| COPOLYMERS OF 2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID/MALEIC ACID： SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY |
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| 引用本文： | Cengiz Soykan Ramazan Coskun Ali Delibas Ertan Sahin. COPOLYMERS OF 2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID/MALEIC ACID： SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY[J]. 高分子科学, 2007, 0(5): 491-500 |
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| 作者姓名： | Cengiz Soykan Ramazan Coskun Ali Delibas Ertan Sahin |
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| 作者单位： | [1]Department of Chemistry, Faculty of Science and Arts, University of Bozok, Yozgat, Turkey [2]Department of Chemistry, Faculty of Science and Arts, University of Ataturk, Erzurum, Turkey |
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| 摘 要： | 2-Acrylamido-2-methy1-1-propanesulfonic acid(AMPS),and maleic acid(MA)copolymerized with different feed ratios using N,N-dimethylformamide as a solvent and benzoyl peroxide(Bz_2O_2)as an initiator at 70℃.Structure and composition of copolymers for a wide range of monomer feed were determined by elemental analysis(content of N for AMPS-units).Monomer reactivity ratios for AMPS(M_1)-MA(M_2)pair were determined by the application of conventional linearization methods such as Fineman-Ross(F-R),Kelen-Tüd(?)s(KT)and Extended Kelen-Tüds(EKT)and a nonlinear error invariable model method using a computer program RREVM.The characterizations were done by Fourier transform infrared spectroscopy(FTIR),differential scanning calorimetry(DSC)thermal gravimetry analysis(TGA),and and X-ray diffraction.The antimicrobial effects of polymers were also tested on various bacteria,and yeast.
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| 关 键 词： | 聚合物 马来酸 热解重量分析 单体反应率 抗菌活性 |
| 收稿时间： | 2006-08-21 |
| 修稿时间： | 2006-08-21 |
COPOLYMERS OF 2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID/MALEIC ACID: SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY |
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| Cengiz Soykan,Ramazan Co,kun,Ali Deliba,Ertan ahin. COPOLYMERS OF 2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID/MALEIC ACID: SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY[J]. Chinese Journal of Polymer Science, 2007, 0(5): 491-500 |
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| Authors: | Cengiz Soykan Ramazan Co kun Ali Deliba Ertan ahin |
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| Affiliation: | Department of Chemistry, Faculty of Science and Arts, University of Bozok, Yozgat, TurkeyDepartment of Chemistry, Faculty of Science and Arts, University of Atatürk, Erzurum, Turkey |
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| Abstract: | 2-Acrylamido-2-methyl-1-propanesulfonic acid (AMPS),and maleic acid (MA)copolymerized with different feed ratios using N,N-dimethylformamide as a solvent and benzoyl peroxide (Bz2O2) as an initiator at 70℃.Structure and composition of copolymers for a wide range of monomer feed were determined by elemental analysis (content of N for AMPS-units).Monomer reactivity ratios for AMPS(M1)-MA(M2) pair were determined by the application of conventional lineartion methods such as Fineman-Ross(F-R),Kelen-Tüd(o)s(KT)and Extended Kxtended Kelen-Tüd(o)s(EKT) and a nonlinear error invariable model method using a computer program RREVM.The characterizations were done by Fourier transform infrared spectroscopy (FTIR),differential scanning calorimetry (DSC) thermal gravimetry analysis (TGA),and and Ⅹ-ray diffraction.The antimicrobial effects of polymers were also tested on various bacteria,and yeast. |
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| Keywords: | Poly(2-acrylamido-2-methyl-1-propanesulfonic acid-co-maleic acid) Thermogravimetric analysis SEM analysis Monomer reactivity ratios. ACID COPOLYMERS SYNTHESIS ANTIMICROBIAL ACTIVITY yeast effects polymers bacteria diffraction thermal analysis differential scanning calorimetry FTIR Fourier transform infrared spectroscopy nonlinear error model |
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