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单粒反应器技术及其模型分析
引用本文:王尤崎,郑绳安.单粒反应器技术及其模型分析[J].复旦学报(自然科学版),1987(1).
作者姓名:王尤崎  郑绳安
作者单位:复旦大学化学系,复旦大学化学系 八四届硕士研究生
摘    要:本文详细分析了单粒反应器技术(single pellet reactor technique)测量二元扩散孔体系扩散系数的数学模型,修正了Hashimoto和Smith等人提出的微孔有效扩散系数计算公式.对分子作可逆线性吸附的假设,用矩分析方法得到了体系大孔和微孔有效扩散系数计算的完整公式.

关 键 词:扩散  沸石  矩分析

MODEL ANALYSIS OF SINGLE PELLET REACTOR WITH BIDISPERSE POROUS DIFFUSION SYSTEM
Wang Youqi,Zheng Shengan.MODEL ANALYSIS OF SINGLE PELLET REACTOR WITH BIDISPERSE POROUS DIFFUSION SYSTEM[J].Journal of Fudan University(Natural Science),1987(1).
Authors:Wang Youqi  Zheng Shengan
Affiliation:Department of Chemistry
Abstract:The model of single pellet reactor in measuring diffusion coefficients of bidisperse porous system has been analysed in detail and the formula for the calculation of micropore diffusion proposed by Hashimoto and Smith has been modified. A whole set of formula for calculating macropore diffusion coefficient D_(?) and micropore diffusion coefficien D_(?) under three different types of inlet pulse have been listed with the supposi(?)ion of reversible linear adsorption.
Keywords:diffusion  zeolite  moment analysis  
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