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Temperature dependence of excited-state relaxation processes of Pr in Pr-doped and Pr, Gd-doped CsCdBr3
Authors:Yizhe An
Affiliation:Department of Chemistry, University of South Dakota, Vermillion, SD 57069, USA
Abstract:The temperature dependence and mechanisms for relaxation of the 1D2 and 3P1 states of Pr3+ in symmetrical Pr-Pr and Pr-Gd pairs in 0.12% Pr:CsCdBr3 and 0.025% Pr:1.5% Gd:CsCdBr3, respectively, are presented. Both single-ion and pair relaxation mechanisms are considered. The temperature dependences of the energy-transfer processes in Pr-Pr pairs are all well-explained in terms of resonance considerations for the donor and acceptor zero-phonon crystal-field transitions.
Keywords:78  55  Hx
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