| 由乙腈一步法制备乙酸丁酯的研究 |
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| 引用本文： | 徐群,安红,周玉梅.由乙腈一步法制备乙酸丁酯的研究[J].精细石油化工,2002(4):27-28. |
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| 作者姓名： | 徐群 安红 周玉梅 |
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| 作者单位： | 1. 齐齐哈尔大学化工学院,161006
2. 齐化化工有限责任公司,161006 |
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| 摘 要： | 以丁醇和制备丙烯腈的副产物乙腈为原料 ,采用一步法合成了乙酸丁酯。通过正交实验得到了影响反应的 4种因素。确定了最佳的工艺条件为 :催化剂的量为样品质量的 40 % ;n(CH3CN)∶ n(C4 H9OH) =1∶ 1 .0 5 ;反应温度为 1 0 5℃ ;反应时间为 8h。在此反应条件下 ,乙酸丁酯的收率为 88.8% ,纯度可达 99.5 %。并用气相色谱及红外光谱对产品的纯度进行了表征
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| 关 键 词： | 乙腈 乙酸丁酯 一步法 合成 |
| 修稿时间： | 2001年7月7日 |
SYNTHESIS OF BUTYL ACETATE FROM ACETONITRILE BY ONE-STEP METHOD |
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| Xu Qun ,An Hong and Zhou Yumei.SYNTHESIS OF BUTYL ACETATE FROM ACETONITRILE BY ONE-STEP METHOD[J].Speciality Petrochemicals,2002(4):27-28. |
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| Authors: | Xu Qun An Hong and Zhou Yumei |
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| Affiliation: | Xu Qun 1,An Hong 1 and Zhou Yumei 2 |
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| Abstract: | Butyl acetate was synthesized from acetonitrile and butanol by one-step method. The effects of four factors on product yield were determined by orthogonal design.The optimum conditions were as follows: reaction temperature 105 ℃, reaction time 8 h, n (CH 3CN) ∶ n (C 4H 9OH)= 1∶ 1.05 , amount of catalyst 40% based on gross weight of reacting substances ,the yield of butyl acetate reached 88.6%, the purity of product was 99.5%. The structure of product was characterized by IR spectrum |
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| Keywords: | acetonitrile butyl acetate one step method synthesis |
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