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序批式膜生物反应器处理生活污水的特性
引用本文:赵英,白晓琴,张颖,顾平.序批式膜生物反应器处理生活污水的特性[J].化工学报,2005,56(11):2195-2199.
作者姓名:赵英  白晓琴  张颖  顾平
作者单位:天津大学环境科学与工程学院,天津 300072
基金项目:国家高技术研究发展计划资助项目(2002AA601240).
摘    要:研究了中试规模序批式膜生物反应器处理生活污水的特性.发现其对CODCr、NH3-N及TN的去除效果可分别达到95.0%、96.3%及38.0%;过膜阻力增加率为1.032 kPa•m-1.TN去除率偏低的主要原因在于缺少搅拌装置,在静置阶段时,污泥大部分沉积在反应器底部(系统运行期间30 min沉降比均低于40%),从而使反硝化细菌不能充分与水溶液中的NOx-N接触.采用空间排阻液相色谱法对混合液及膜污染物进行分子量分布测定,发现大量大分子物质在反应器内、膜面及膜孔内积累,相对分子质量大于104的有机物分别占64.0%、38.0%.经过物理及化学清洗,膜通量恢复了73.4%,多糖含量为清洗前的30.4%,说明多糖是造成不可逆污染的主要物质.

关 键 词:序批式膜生物反应器  膜污染  分子量分布
文章编号:0438-1157(2005)11-2195-05
收稿时间:11 30 2004 12:00AM
修稿时间:2004-11-302005-02-02

Characteristics of membrane sequencing batch reactor for domestic wastewater treatment
ZHAO Ying,BAI Xiaoqin,ZHANG Ying,GU Ping.Characteristics of membrane sequencing batch reactor for domestic wastewater treatment[J].Journal of Chemical Industry and Engineering(China),2005,56(11):2195-2199.
Authors:ZHAO Ying  BAI Xiaoqin  ZHANG Ying  GU Ping
Abstract:The characteristics of pilot-scale membrane sequencing batch reactor (MSBR) treating synthetic wastewater were studied.The CODCr, NH3-N and TN removal were 95.0%,96.3% and 38.0% respectively.The reason for low TN removal was lacking agitated equipment. During static phase, most sludge settled to the bottom of reactor (SV<40%),and consequently the denitrifying bacteria could not contact with NOx-N completely. The trans-membrane pressure (TMP) rise rate was 1.032 kPa&#8226;m-1. Molecular weight distribution of mixed liquid and membrane foulants were analyzed by the steric exclusion liquid chromatography method. It demonstrated that the accumulation of macromolecular matter(molecular weight>104) in reactor and membrane were 64.0% and 38.0% respectively. After physical and chemical washing, membrane specific flux was recovered by 73.4%. The concentration of polysaccharides deposited on the membrane was reduced to 30.4%. Polysaccharide was the important substance to cause irreversible fouling.
Keywords:membrane sequencing batch reactor  membrane fouling  molecular weight distribution
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