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Ferroelectricity of perovskites under pressure
Authors:Kornev Igor A  Bellaiche L  Bouvier P  Janolin P-E  Dkhil B  Kreisel J
Affiliation:Physics Department, University of Arkansas, Fayetteville, Arkansas 72701, USA. ikornev@uark.edu
Abstract:Ab initio simulations and experimental techniques are combined to reveal that, unlike what was commonly accepted for more than 30 years, perovskites and related materials enhance their ferroelectricity as hydrostatic pressure increases above a critical value. This unexpected high-pressure ferroelectricity is different in nature from conventional ferroelectricity because it is driven by an original electronic effect rather by long-range interactions.
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