| 锡酞菁及其磺化衍生物的合成与性质研究 |
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| 引用本文： | 殷焕顺,邓建成.锡酞菁及其磺化衍生物的合成与性质研究[J].电子元件与材料,2006,25(4):53-56. |
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| 作者姓名： | 殷焕顺 邓建成 |
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| 作者单位： | 湘潭大学化学学院,湖南,湘潭,411105;山东农业大学化学与材料科学学院,山东,泰安,271018;湘潭大学化学学院,湖南,湘潭,411105 |
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| 摘 要： | 以苯酐和氯化亚锡为原料,采用固相法合成锡酞菁(SnPc),再和发烟硫酸反应合成磺化锡酞菁(SnPcS)。用元素分析,红外光谱,紫外光谱对它们进行了表征。结果表明:磺化锡酞菁的溶解性比锡酞菁要大得多;热稳定性研究发现,磺化锡酞菁从100℃开始失去磺酸基,400℃酞菁环才开始分解;且磺化锡酞菁在水中的氧化还原过程具有可逆性;同时,对磺化锡酞菁的电子光谱进行了研究。
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| 关 键 词： | 有机化学 锡酞菁 磺化锡酞菁 固相法 |
| 文章编号： | 1001-2028（2006）04-0053-04 |
| 收稿时间： | 2005-10-28 |
| 修稿时间： | 2005-10-28 |
Synthesis and Properties for Tin Phthalocyanine and Its Sulfonated Derivative |
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| YIN Huan-shun,DENG Jian-cheng.Synthesis and Properties for Tin Phthalocyanine and Its Sulfonated Derivative[J].Electronic Components & Materials,2006,25(4):53-56. |
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| Authors: | YIN Huan-shun DENG Jian-cheng |
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| Affiliation: | 1. College of Chemistry, Xiangtan University, Xiangtan 411105, China; 2. College of Chemistry and Material Science, Shandong Agriculture University, Tai an 271018, China |
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| Abstract: | Tin phthalocyanine and its sulfonated derivated were synthesized by solid phase method.The structures of products were characterized by IR,UV-VIS spectra and element analysis.Two or three hydrogens atoms in phthalocyanine benzene rings were substituted by sulfonic group.Obtained results show that sulfonated tin phthalocyanine has good solubility in water and organic solvents.The sulfonic group will decompose from 100℃ to 400℃,and then the phthalocyanine ring will decompose.The properties of spectrum and electrochemistry were also researched. |
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| Keywords: | organic chemistry tin phthalocyanine sulfonated tin phthalocyanine solid phase method |
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