| 四氯化锡催化合成氯乙酸异丙酯 |
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| 引用本文： | 吴东辉,罗军,杨绪杰. 四氯化锡催化合成氯乙酸异丙酯[J]. 合成化学, 2001, 9(4): 347-349 |
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| 作者姓名： | 吴东辉 罗军 杨绪杰 |
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| 作者单位： | 1. 南京理工大学材料化学教研室,江苏,南京,210094
2. 南京理工大学精细化工教研室,江苏,南京,210094 |
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| 摘 要： | 四氯化锡对由氯乙酸和异丙醇合成氯乙酸异丙酯的酯化反应具有较高的催化活性和选择性。当SnCI4量为2．0％（w）时，反应4h，氯乙酸异丙酯的产率为77．0％，纯度达97．9％。
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| 关 键 词： | 氯乙酸异丙酯 四氯化锡 催化酯化 氯乙酸 异丙醇 催化活性 |
| 文章编号： | 1005-1511(2001)04-347-03 |
| 修稿时间： | 2000-06-15 |
Synthesis of Isopropyl Chloroacetate Catalyzed by SnCl4 |
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| WU Dong hui ,LUO Jun ,YANG Xu jei. Synthesis of Isopropyl Chloroacetate Catalyzed by SnCl4[J]. Chinese Journal of Synthetic Chemistry, 2001, 9(4): 347-349 |
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| Authors: | WU Dong hui LUO Jun YANG Xu jei |
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| Affiliation: | WU Dong hui 1,LUO Jun 2,YANG Xu jei 2 |
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| Abstract: | SnCl 4 has high catalytic activity and selectivity in the synthesis of isopropyl chloroacetate from isopropanol and chloroacetic acid. Under the optimum reactive conditions[amount of SnCl 4 2.0%(w), reaction time 4h] the yield and purity of isopropyl chloroacetate were 77.0% and 97.9% respectively. |
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