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新型铜基块体非晶合金Cu55-xZr37Ti8Inx的制备及性能
引用本文:皮锦红,潘冶,吴继礼,张露,贺显聪. 新型铜基块体非晶合金Cu55-xZr37Ti8Inx的制备及性能[J]. 中国有色金属学会会刊, 2013, 23(10): 2989-2993. DOI: 10.1016/S1003-6326(13)62825-3
作者姓名:皮锦红  潘冶  吴继礼  张露  贺显聪
作者单位:1. 东南大学 材料科学与工程学院,江苏省先进金属材料重点实验室,南京 211189; 南京工程学院 材料工程学院,南京 211167
2. 东南大学 材料科学与工程学院,江苏省先进金属材料重点实验室,南京 211189
3. 南京工程学院 材料工程学院,南京,211167
基金项目:Project (50971041) support by the National Natural Science Foundation of China
摘    要:利用铜模吸铸法合成Cu—ZrTi—In非晶棒。块体非晶合金Cu50Zr37Ti8In5的△瓦值最大,为66K。从原子尺寸大小和热力学角度分析在铜基非晶合金中添加适量In元素后能够提高其非晶形成能力的原因。在所测的块体非晶合金Cu55.Zr37Ti8Inx(x≤〈5),Cu52Zr37Ti8In3表现出最高的抗压强度(1981MPa)和最佳的塑性,其在压缩断裂前的总塑性变形量约为1.2%。

关 键 词:Cu—Zr-Ti—In合金    Cu基合金  块体非晶合金  非晶形成能力  力学性能
收稿时间:2012-09-12

Preparation and properties of novel Cu-based bulk metallic glasses Cu55-xZr37Ti8Inx
Jin-hong PI,Ye PAN,Ji-li WU,Lu ZHANG,Xian-cong HE. Preparation and properties of novel Cu-based bulk metallic glasses Cu55-xZr37Ti8Inx[J]. Transactions of Nonferrous Metals Society of China, 2013, 23(10): 2989-2993. DOI: 10.1016/S1003-6326(13)62825-3
Authors:Jin-hong PI  Ye PAN  Ji-li WU  Lu ZHANG  Xian-cong HE
Affiliation:1. Jiangsu Key Laboratory for Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China; 2. School of Materials Engineering, Nanjing Institute of Technology, Nanjing 211167, China Received 12 September 2012; accepted 18 May 2013)
Abstract:The glassy rods were successfully fabricated in the Cu-Zr-Ti-In alloy system by casting into a copper mold. The value of ATx reaches a maximum of 66 K for the BMG CusoZraTTi8In5 alloy. The reasons for enhancing glass forming ability of Cu-based BMGs with the addition of indium were discussed from atomic size and thermodynamics. Alternatively, the BMG Cu52Zra7Ti8In3 exhibits the highest compressive strength (1981 MPa) and the best plasticity among glassy Cu55-xZra7TisInx (x_〈5). The total plastic deformation of Cu52Zr37TisIn3 before fracture approaches 1.2%.
Keywords:Cu-Zr-Ti-In alloy  indium  Cu-based alloy  bulk metallic glass  glass forming ability  mechanical properties
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