| Self-assembly of Carboxyl Functionalized Polystyrene Nanospheres into Close-packed Monolayers via Chemical Adsorption |
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| 作者姓名： | 李志伟 周静芳 张治军 党鸿辛 |
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| 作者单位： | [1]KeyLaboratoryofSpecialFunctionalMaterialsofHenanProvince,HenanUniversity,Kaifeng,Henan475001,China [2]StateKeyLaboratoryofSolidLubrication,LanzhouInstituteofChemicalPhysics,ChineseAcademyofSciences,Lanzhou,Gansu730000,China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 20271016) and the Natural Science Award for Outstanding Youth of Henan Province (No. 212000600). |
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| 摘 要： | The polyacrylic acid functionalized polystyrene nanospheres were synthesized and self-assembled into irregular, densely packed monolayers in non-aqueous media. The polymer nanoparticles were chemically adhered to substrates. The morphologies of the resulting films were investigated. The impact of the volume fraction of alcohol in the mixed solvents on the particle adsorption and fabrication of nanosphere assembled films was examined.
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| 关 键 词： | 自组装 化学吸附 聚苯乙烯／聚丙烯酸 纳米微球 单层膜 羟基化作用 |
Self-assembly of Carboxyl Functionalized Polystyrene Nano-spheres into Close-packed Monolayers via Chemical Adsorption |
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| LI,Zhi-Wei ZHOU,Jing-Fang ZHANG,Zhi-Jun DANG,Hong-Xin,Key Laboratory of Special Functional Materials of Henan Province,Henan University,Kaifeng,Henan ,China State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou,Gansu ,China.Self-assembly of Carboxyl Functionalized Polystyrene Nanospheres into Close-packed Monolayers via Chemical Adsorption[J].Chinese Journal of Chemistry,2004,22(10):1133-1137. |
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| Authors: | LI Zhi-Wei ZHOU Jing-Fang ZHANG Zhi-Jun DANG Hong-Xin Key Laboratory of Special Functional Materials of Henan Province Henan University Kaifeng Henan China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou Gansu China |
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| Affiliation: | LI,Zhi-Wei ZHOU,Jing-Fang ZHANG,Zhi-Jun DANG,Hong-Xin,Key Laboratory of Special Functional Materials of Henan Province,Henan University,Kaifeng,Henan 475001,China State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou,Gansu 730000,China |
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| Abstract: | The polyacrylic acid functionalized polystyrene nanospheres were synthesized and self-assembled into irregular, densely packed monolayers in non-aqueous media. The polymer nanoparticles were chemically adhered to sub-strates. The morphologies of the resulting films were investigated. The impact of the volume fraction of alcohol in the mixed solvents on the particle adsorption and fabrication of nanosphere assembled films was examined. |
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| Keywords: | self-assembly polystyrene/polyacrylic acid nanosphere |
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