| 全氟羧酸酯乙烯基醚的合成研究 |
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| 引用本文： | 陈焱锋,吴君毅.全氟羧酸酯乙烯基醚的合成研究[J].有机氟工业,2014(3):4-5. |
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| 作者姓名： | 陈焱锋 吴君毅 |
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| 作者单位： | 上海三爱富新材料股份有限公司 |
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| 摘 要： | 全氟羧酸酯乙烯基醚用于多种含氟聚合物的改性,合成全氟羧酸离子交换树脂等高性能含氟聚合物,也可以合成含氟醚类的绿色可降解表面活性剂。采用3-羧酸甲酯全氟丙酰氟与六氟环氧丙烷进行加成反应,然后脱羧制备全氟羧酸酯乙烯基醚。
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| 关 键 词： | 3-羧酸甲酯全氟丙酰氟 全氟羧酸酯乙烯基醚 六氟环氧丙烷 |
Synthesis of Perfluorocarboxylic Ester Vinyl Ether |
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| Chen Yanfeng;Wu Junyi.Synthesis of Perfluorocarboxylic Ester Vinyl Ether[J].Organo-Fluorine Industry,2014(3):4-5. |
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| Authors: | Chen Yanfeng;Wu Junyi |
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| Affiliation: | Chen Yanfeng;Wu Junyi;Shanghai 3F New Materials Co. ,Ltd.; |
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| Abstract: | carboxylic acid Perfluorocarboxylic ester vinyl ether was used for modified fluoropolymers, synthetic perfluorinated ion exchange resin, also can be synthesized biodegradable surfaetants agent of fluorinated ethers. In this paper, we ussed 3 - methyl carboxylate perfluorinated propionyl fluoride and hexafluoropropene oxide by addi- tion reaction, and then deearboxylation preparing perfluorocarboxylic ester vinyl ether. |
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| Keywords: | perfluorocarboxylic ester vinyl ether hexafluoropropene oxide synthesis technique |
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