| 单（2─乙基已基）磷酸萃取剂皂化体系微乳液的研究 |
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| 引用本文： | 潘莹,胡正水,于卉,傅洵,赵松山,于秀芳. 单（2─乙基已基）磷酸萃取剂皂化体系微乳液的研究[J]. 青岛科技大学学报(自然科学版), 1995, 0(4) |
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| 作者姓名： | 潘莹 胡正水 于卉 傅洵 赵松山 于秀芳 |
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| 作者单位： | 青岛化工学院，青岛职工大学，曲阜师范大学 |
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| 摘 要： | 研究了单（２─乙基己基）磷酸钠盐─醇─有机溶剂─水体系微乳液的形成条件，用稀释法测定了热力学函数△Ｇ０→ｉ，并求得了酸式盐ＮａＨＡ─醇－正己烷－水体系微乳液的结构参数，讨论了有机溶剂、醇、温度对△Ｇ０→ｉ的影响及醇碳链长度与微乳液结构参数的关系。
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| 关 键 词： | 单（2─乙基已基）磷酸；萃取剂；微乳液；热力学函数；结构参数 |
Microemulsion for System of Saponified Mono(2-ethylhexyl) Phosphoric Acid |
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| Pan Ying, Hu Zhengshui, Yu Hui, Fu Xun. Microemulsion for System of Saponified Mono(2-ethylhexyl) Phosphoric Acid[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1995, 0(4) |
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| Authors: | Pan Ying Hu Zhengshui Yu Hui Fu Xun |
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| Affiliation: | Pan Ying; Hu Zhengshui; Yu Hui; Fu Xun(Qingdao Institute of Chemical Technology)Zhao Songshan; Yu Xiufang(Qingdao Worker's University)(Qufu Normal University) |
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| Abstract: | The microemulsion formation conditions for sodium salt of mono(2-ethylhexyl) phosphoric act d-alcohol-solvent-water system have been investiguted. The thermodynamic function has been determined and some structure parameters have been calculated based on the model of w/o microemulsion. The effect of solvent, alcohol and temperature on △G and the relationship between chain length of alcohol and the structure parameters are dealt with. |
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| Keywords: | mono (2-ethylhexyl) Phosphoric acid extractant microemulsion thermodynamic function structure parameter |
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