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Corrosion resistance of TiO2 films grown on stainless steel by atomic layer deposition
Authors:C.X. Shan
Affiliation:School of Mechanical, Materials and Manufacturing Engineering, The University of Nottingham, University Park, Nottingham, NG7 2RD, United Kingdom
Abstract:Titanium dioxide (TiO2) films have been deposited onto stainless steel substrates using atomic layer deposition (ALD) technique. Composition analysis shows that the films shield the substrates entirely. The TiO2 films are amorphous in structure as characterized by X-ray diffraction. The electrochemical measurements show that the equilibrium corrosion potential positively shifts from − 0.96 eV for bare stainless steel to − 0.63 eV for TiO2 coated stainless steel, and the corrosion current density decreases from 7.0 × 10− 7 A/cm2 to 6.3 × 10− 8 A/cm2. The corrosion resistance obtained by fitting the impedance spectra also reveals that the TiO2 films provide good protection for stainless steel against corrosion in sodium chloride solution. The above results indicate that TiO2 films deposited by ALD are effective in protecting stainless steel from corrosion.
Keywords:61. 10. Nz   68. 55.-a   81. 15. Gh   82. 45. Mp   82. 45. Bb
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