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SrFCl:Eu~(2+)晶体的电子自旋共振谱研究
引用本文:陈伟,苏勉曾,韩世莹.SrFCl:Eu~(2+)晶体的电子自旋共振谱研究[J].北京大学学报(自然科学版),1993(6).
作者姓名:陈伟  苏勉曾  韩世莹
作者单位:北京大学化学系,北京大学化学系,南京大学材料分析中心 北京科技大学材料物理系
摘    要:用程序降温法生长了SrFCl:Eu~(2+)晶体,并测量了它的电子自旋共振谱。应用最小二乘法拟合技术对g因子及自旋哈密顿参数进行了精确拟合。报道了各向异性的g因子及有关自旋哈密顿参量。发现并归属了Eu~(2+)的高阶禁阻跃迁。

关 键 词:SrFCl:Eu~(2+)  电子自旋共振谱  最小二乘法拟合技术  g因子  禁阻跃迁

The Electron Spin Resonance Study of SrFCl:Eu~(2+) Crystal
CHEN Wei,SU Mianzeng.The Electron Spin Resonance Study of SrFCl:Eu~(2+) Crystal[J].Acta Scientiarum Naturalium Universitatis Pekinensis,1993(6).
Authors:CHEN Wei  SU Mianzeng
Abstract:The SrFCl:Eu2+ single crystal was grown by programmed cooling method, and its electron spin resonance (ESR) spectra were recorded. The g factors and ESR parameters were simulated with the Least-Square Fitting Method. The anisotropic g factors and related spin Hamiltonian parameters were reported. High-order forbbiden transition of Eu2+ in SrFCl:Eu2+ crystal were observed and assigned according to the calculation results.
Keywords:SrFClEu2+  Electron spin resonance spectra  Least-square fitting method  g-Factor  Forbbiden transition
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