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Enhancing the performance of photovoltaic cells by using down-converting KCaGd(PO_4)_2:Eu~(3+) phosphors
引用本文:陈彦吉,黄琬妤,陈登铭. Enhancing the performance of photovoltaic cells by using down-converting KCaGd(PO_4)_2:Eu~(3+) phosphors[J]. 中国稀土学报(英文版), 2011, 29(9): 907-910. DOI: 10.1016/S1002-0721(10)60565-0
作者姓名:陈彦吉  黄琬妤  陈登铭
作者单位:Phosphors Research Laboratory and Department of Applied Chemistry;National Chiao Tung University;
基金项目:Project supported by National Science Council of Taiwan (NSC98-2113-M-009-005-MY3)
摘    要:The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic (PV) cells by using the solar spectral conversion principle, which employed a down-converting phosphor to convert a high-energy ultraviolet photon to the less energetic red-emitting photons to improve the spectral response of Si solar cells. In this study, the surface of silicon solar cells was coated with a red-emitting KCaGd(PO4)2:Eu3+ phosphor by using the screen-printing technique. In addition to the investigation on the microstructure using scanning electron microscopy (SEM), we measured the short circuit current (Isc), open circuit voltage (Voc), and power conversion efficiency (η) of spectral-conversion cells and compared with those of bare solar cells as a reference. Preliminary experimental results revealed that in an optimized PV cell, an enhancement of (0.64+0.01)% (from 16.03% to 16.67%) in Δη of a Si-based PV cell was achieved.

关 键 词:solar cells  down-converting phosphor  KCaGd(PO4)2:Eu3+  screen-printing  rare earths
收稿时间:2011-04-08

Enhancing the performance of photovoltaic cells by using down-converting KCaGd(PO_4)_2:Eu~(3+) phosphors
Yen-Chi Chen,Woan-Yu Huang,Teng-Ming Chen. Enhancing the performance of photovoltaic cells by using down-converting KCaGd(PO_4)_2:Eu~(3+) phosphors[J]. Journal of Rare Earths, 2011, 29(9): 907-910. DOI: 10.1016/S1002-0721(10)60565-0
Authors:Yen-Chi Chen  Woan-Yu Huang  Teng-Ming Chen
Affiliation:Yen-Chi Chen,Woan-Yu Huang,Teng-Ming Chen (Phosphors Research Laboratory and Department of Applied Chemistry,National Chiao Tung University,Hsinchu 30010,Taiwan,China)
Abstract:The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic (PV) cells by using the solar spectral conversion principle, which employed a down-converting phosphor to convert a high-energy ultraviolet photon to the less energetic red-emitting photons to improve the spectral response of Si solar cells. In this study, the surface of silicon solar cells was coated with a red-emitting KCaGd(PO4)2:Eu3+ phosphor by using the screen-printing technique. ...
Keywords:solar cells  down-converting phosphor  KCaGd(PO4)2:Eu3   screen-printing  rare earths  
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