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Permeability of High-Alumina Refractory Castables Based on Various Hydraulic Binders
Authors:Murilo D M Innocentini  Arturo R F Pardo  Victor C Pandolfelli  Bruno A Menegazzo  Luis R M Bittencourt  Roberto P Rettore
Affiliation:Department of Materials Engineering, Federal University of São Carlos, São Carlos, São Paulo 13565–905, Brazil;Alcoa Alumínio S.A., São Paulo, São Paulo 05804–900, Brazil;Magnesita Research Center, Contagem, Minas Gerais, 32210–050, Brazil
Abstract:This work investigated the changes in the permeability of high-alumina self-flowing refractory castables based on calcium aluminate cement (CAC) and hydratable alumina binder (HAB) pretreated between 110° and 1650°C. Permeability constants k 1 and k 2 were fitted from Forchheimer's equation based on airflow tests conducted at room temperature. The results indicated that dehydration was the main contributing factor for increased permeability in bodies pretreated up to 600°C and that sintering effects prevailed between 900° and 1650°C. Castables based on HAB were less permeable than those based on CAC, a behavior ascribed to the type of hydrates formed and to the particle-packing features of the matrix and the matrix–aggregate interfaces.
Keywords:cement  refractories  alumina  permeability  calcium aluminate
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