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Surface modification of armos fibers with oxygen plasma treatment for improving interfacial adhesion with poly(phthalazinone ether sulfone ketone) resin
Authors:Jing Wang  Ping Chen  Wei Liu  Hong Li  Caixia Jia  Chun Lu  Baichen Wang
Affiliation:1. State Key Laboratory of Material Surface Modification by Laser, Ion and Electronic Beams, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China;2. Center for Composite Materials, Shenyang Institute of Aeronautical Engineering, Shenyang 110034, China;3. Dalian Education University, Dalian 116021, China
Abstract:We introduce in this article oxygen plasma treatment as a convenient and effective method for the surface modification of Armos fibers. The effects of oxygen‐plasma‐treatment power on both the Armos fiber surface properties and Armos‐fiber‐reinforced poly(phthalazinone ether sulfone ketone) composite interfacial adhesion were investigated. The Armos fiber surface chemical composition, surface morphology and roughness, and surface wettability as a function of oxygen‐plasma‐treatment power were measured by X‐ray photoelectron spectroscopy, scanning electronic microscopy, atomic force microscopy, and dynamic contact angle analysis. The results show that oxygen plasma treatment introduced a lot of reactive functional groups onto the fiber surface, changed the surface morphology, increased the surface roughness, and enhanced the surface wettability. Additionally, the effect of the oxygen‐plasma‐treatment power on the composite interfacial adhesion was measured by interlaminar shear strength with a short‐beam bending test. Oxygen plasma treatment was an effective method for improving the composite interfacial properties by both chemical bonding and physical effects. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
Keywords:adhesion  composites  fibers  interfaces  surface
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