反相液相色谱作用指数温度效应的研究 |
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引用本文: | 张玉奎 ,陈农 ,卢佩章. 反相液相色谱作用指数温度效应的研究[J]. 分析测试学报, 1989, 0(6) |
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作者姓名: | 张玉奎 陈农 卢佩章 |
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摘 要: | 本文研究了反相液相色谱作用指数C的温度效应对给定溶质、温度升高,C值降低;并符合近似的状态方程。在此基础上预测了不同温度、不同冲洗剂浓度的溶质下保留值、预测值与实测值基本一致。
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关 键 词: | 作用指数 温度效应 反相液相色谱 |
Investigation of Temperature Effects on Interaction Index of RPHPLC |
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Abstract: | We found that the interaction Index of RPHPLC for a given solute decrease as thecolumn temperature going op. The decreases are in accordance with the following equation:in K'=A C C_B B lnC_Band solute retention values at different column temperatures at different eluent concentrationscan be predicted based on the equation mentioned above. |
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Keywords: | Interaction index temperature effect RP liquid chromatography |
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