| 新型储氢材料及其热力学与动力学问题 |
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| 引用本文： | 孙立贤,宋莉芳,姜春红,刘淑生,焦成丽,王爽,司晓亮,张箭,李芬,徐芬,黄风雷.新型储氢材料及其热力学与动力学问题[J].中国科学:化学,2010(9):1243-1252. |
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| 作者姓名： | 孙立贤 宋莉芳 姜春红 刘淑生 焦成丽 王爽 司晓亮 张箭 李芬 徐芬 黄风雷 |
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| 作者单位： | [1]中国科学院大连化学物理研究所材料热化学实验室,洁净能源国家实验室（筹）,大连116023 [2]中国科学院研究生院,北京100049 [3]辽宁师范大学化学化工学院,大连116029 [4]爆炸科学与技术国家重点实验室（北京理工大学）北京理工大学机电工程学院,北京100081 |
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| 基金项目： | 国家自然科学基金（U0734005 20833009 20873148 20903095）; 国家重点基础研究发展计划（2010CB631303）; 大连市科学技术基金（2009A11GX052）; 北京理工大学爆炸科学与技术国家重点实验室开放基金（KFJJ10-1Z）资助 |
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| 摘 要： | 氢能作为一种理想的二次能源受到了国内外科研工作者的广泛关注,研制可以在室温和较低压力下方便、安全、高效地储存氢能的材料是氢能发展的瓶颈.到目前为止,固态储氢材料以能量密度高及安全性好等优势被认为极具应用前景,其中以轻质元素构成的氢化物(包括硼氢化物/铝氢化物(可用通式A(MH4)n表示,其中A是碱金属(Li,Na,K)或碱土金属(Be,Mg,Ca);M是硼或铝;n=1～4)、氨基氢化物(如LiNH2等))、氨硼烷(NH3BH3)、金属有机骨架材料(MOFs)是新型储氢材料研究领域的热点,本文将着重就目前这几类储氢材料的研究当中所涉及到的一些热力学及动力学问题进行总结探讨.
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| 关 键 词： | 储氢材料 氢化物 金属有机骨架材料 热力学 动力学 |
Thermodynamics and kinetics of new hydrogen storage materials |
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| SUN LiXian,SONG LiFang,JIANG ChunHong,LIU ShuSheng,JIAO ChengLi,Wang Shuang,SI XiaoLiang,ZHANG Jian,LI Fen,XU Fen,＆ HUANG FengLei.Thermodynamics and kinetics of new hydrogen storage materials[J].Scientia Sinica Chimica,2010(9):1243-1252. |
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| Authors: | SUN LiXian SONG LiFang JIANG ChunHong LIU ShuSheng JIAO ChengLi Wang Shuang SI XiaoLiang ZHANG Jian LI Fen XU Fen ＆ HUANG FengLei |
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| Affiliation: | 1 Dalian National Laboratory of Clean Energy;Materials and Thermochemistry Laboratory,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China 2 Graduate University of the Chinese Academy of Sciences,Beijing 100049,China 3 Faculty of Chemistry and Chemical Engineering,Liaoning Normal University,Dalian 116029,China 4 State Key Laboratory of Explosion Science and Technology;School of Mechanical Engineering,Beijing Institute of Technology,Beijing 100081,China |
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| Abstract: | Hydrogen attracts great attention as an ideal secondary energy.Hydrogen production and applications have a variety of solutions,but the storage and transportation still faces a great challenge.Solid-state hydrogen storage materials with advantages of high energy density and safety are considered to have very promising prospects.Hydrides of light elements （including boron hydride,aluminum hydride,etc..It is generally expressed as A（MH4）n,where A is alkali metals （Li,Na,K） or alkaline earth metals （Be,Mg,Ca）,and M is B or Al in IIIB family of periodic table,n=1？4）,composite hydrides （like LiBH4-MgH2,etc.）,ammonia borane and metal organic frameworks （MOFs） are remarkable hydrogen storage materials.We will focus on review of these types of hydrogen storage materials and their thermodynamics and kinetics in the present paper. |
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| Keywords: | hydrogen storage materials hydrides metal organic frameworks thermodynamics kinetics |
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