SGTE data for pure elements

Thermodynamic data for the condensed phases of 78 elements as currently used by SGTE (Scientific Group Thermodata Europe) are tabulated. SGTE is a consortium of seven organisations in Western Europe engaged in the compilation of a comprehensive, self consistent and authoritative thermochemical database for inorganic and metallurgical systems. The data are being published here in the hope that they will become widely adopted within the international community as a sound basis for the critical assessment of thermodynamic data, thereby, perhaps, limiting unnecessary duplication of effort. The data for each phase of each element considered aie presented as expressions showing, as a function of temperature, the variation of (a) G-H_SER, the Gibbs energy relative to the enthalpy of the “Standard Element Reference” ie the reference phase for the element at 298.15 K and (b) the difference in Gibbs energy between each phase and this reference phase (ie lattice stability). The variation of the heat capacity of the various phases and the Gibbs energy difference between phases are also shown graphically. For certain elements the thermodynamic data have been assessed as a function of pressure as well as temperature. Where appropriate a temperature— pressure phase diagram is also shown.

Throughout this paper the thermodynamic data are expressed in terms of J mol⁻¹. The temperatures of transition between phases have been assessed to be consistent with the 1990 International Temperature Scale (ITS90).