| 双环戊二烯开环易位聚合反应用催化剂的研究进展 |
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| 引用本文： | 时萌珣,刘前,刘建,段高坤,方超立,杨维成,罗勇.双环戊二烯开环易位聚合反应用催化剂的研究进展[J].上海塑料,2021(1):12-20. |
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| 作者姓名： | 时萌珣 刘前 刘建 段高坤 方超立 杨维成 罗勇 |
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| 作者单位： | 上海化工研究院有限公司;聚烯烃催化技术与高性能材料国家重点实验室;上海市聚烯烃催化技术重点实验室 |
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| 基金项目： | 上海市科委高新技术领域项目(18511109200)。 |
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| 摘 要： | 聚双环戊二烯(PDCPD)是由双环戊二烯(DCPD)聚合而成的高分子化合物,作为一种新型高性能树脂,近年来其市场需求急速发展.为制备PDCPD材料,聚合反应中的催化剂是技术关键,直接决定了产品的性能与制备工艺的经济性.主要基于催化技术的发展过程,从催化剂的结构与功能等方面,介绍了目前DCPD聚合制备PDCPD过程中所采...
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| 关 键 词： | 聚双环戊二烯 开环易位聚合反应 催化剂 |
Development of Catalyst Technology in Ring-opening Metathesis Polymerization of Dicyclopentadiene |
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| SHI Mengxun,LIU Qian,LIU Jian,DUAN Gaokun,FANG Chaoli,YANG Weicheng,LUO Yong.Development of Catalyst Technology in Ring-opening Metathesis Polymerization of Dicyclopentadiene[J].Shanghai Plastics,2021(1):12-20. |
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| Authors: | SHI Mengxun LIU Qian LIU Jian DUAN Gaokun FANG Chaoli YANG Weicheng LUO Yong |
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| Affiliation: | (Shanghai Research Institute of Chemical Industry Co.,Ltd.,Shanghai 200062,China;State Key Laboratory of Polyolefins and Catalysis,Shanghai 200062,China;Shanghai Key Laboratory of Catalysis Polyolefins,Shanghai 200062,China) |
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| Abstract: | Polydicyclopentadiene(PDCPD)is polymerized from dicyclopentadiene(DCPD),performing as an excellent polymer,its market demand is growing rapidly in recent years.In order to prepare PDCPD materials,the catalysts used in the polymerization is the key technology,which directly determine the performance and economics of preparation.Based on the development progress of catalytic technology,from the technical aspects of catalyst structure and function,the main catalysts of DCPD’s polymerization are introduced,and reviewed the development of catalyst technology. |
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| Keywords: | PDCPD ring-opening metathesis polymerization catalyst |
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