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非钯催化剂催化Heck反应研究进展
引用本文:张磊,崔元臣.非钯催化剂催化Heck反应研究进展[J].有机化学,2010,30(2):167-172.
作者姓名:张磊  崔元臣
作者单位:1. 河南大学化学化工学院,开封,475001
2. 河南大学化学化工学院,开封,475001;河南大学特种功能材料实验室,开封,475001
摘    要:非钯催化剂用于催化Heck反应有较多的报道.与钯催化剂相比,一些非钯催化剂(如镍、铜、钴等)显示了更优越的性能.近年来,铂、铑、钌、铁等催化体系也被用于Heck反应.对近年来非钯催化剂用于催化Heck反应的研究进行了归纳总结.

关 键 词:Heck反应  催化  过渡金属  卤代芳烃
收稿时间:2009-03-31
修稿时间:2009-05-28

Progress in Heck Reaction Catalyzed by Non-palladium Catalyst
Zhang Lei,Cui Yuanchen.Progress in Heck Reaction Catalyzed by Non-palladium Catalyst[J].Chinese Journal of Organic Chemistry,2010,30(2):167-172.
Authors:Zhang Lei  Cui Yuanchen
Affiliation:( College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001)
( Laboratory of Special Functional Materials, Henan University, Kaifeng 475001)
Abstract:Many non-palladium catalysts have been applied to Heck reactions. Compared with palladium complexes, some non-palladium catalysts (such as nickel, copper, cobalt complexes, and so on) show many advantages in application. Catalyst systems based on platinum, rhodium, ruthenium or iron were also applied to Heck reactions in recent years. In this paper, the progress in Heck reaction catalyzed by non-palladium catalyst is reviewed.
Keywords:Heck reaction  catalysis  transition metal  aryl halide
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