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Syntheses of Some New Group 4 non-Cp Complexes Bearing Schiff-base, Thiophene Diamide Ligands Respectively and Their Catalytic Activities for α-Olefin Polymerization
引用本文:黄吉玲,廉兵,雍莉,钱延龙.Syntheses of Some New Group 4 non-Cp Complexes Bearing Schiff-base, Thiophene Diamide Ligands Respectively and Their Catalytic Activities for α-Olefin Polymerization[J].中国化学,2004(6).
作者姓名:黄吉玲  廉兵  雍莉  钱延龙
作者单位:Laboratory of Organometallic Chemistry,East China University of Science and Technology,Shanghai 200237,China,Laboratory of Organometallic Chemistry,East China University of Science and Technology,Shanghai 200237,China,Laboratory of Organometallic Chemistry,East China University of Science and Technology,Shanghai 200237,China,Laboratory of Organometallic Chemistry,East China University of Science and Technology,Shanghai 200237,China
基金项目:Project supported by the Special Funds for Major State Basic Research Projects (No. G 1999064801),the National Natural Science Foundation of China (No. 20072004 ) and the Research Fund for the Doctoral Program of High Education (No. 20020251002).
摘    要:Introduction Tremendous advances have been witnessed during the last decade in the syntheses and application of Group 4 metal complexes because of the motivity which comes from both academic and industrial field. Among them, studies have been dominated by the complexes supported by bis or mono cyclopentadienyl ligands, such as Cp2MX2 or half sandwich amide (CGC) com-plexes.1-6 At that time chemists paid a little attention to the non-cyclopentadienyl complexes, but in recent years, many chem…

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