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| 内循环反应器用于气固反应的动力学研究 | |
| 引用本文： | 郭延红,丁永朝,高彩虹.内循环反应器用于气固反应的动力学研究[J].化学与生物工程,2009,26(3). |
| 作者姓名： | 郭延红 丁永朝 高彩虹 |
| 作者单位： | 1. 延安大学化工学院,陕西省化学反应工程省级重点实验室,陕西,延安,716000 2. 延长油田股份有限公司管道公司,陕西,延安,716000 3. 延安市自来水公司,陕西,延安,716000 |
| 摘 要： | 设计了一套用于动力学研究的内循环无梯度反应系统,对其进行了无梯度检验,并用乙醇脱水动力学考证了该系统的可靠性.根据微型反应色谱测得的乙醇在HZSM-5分子筛上脱水反应的动力学数据,首次建立了乙醇脱水反应动力学数学模型的幂函数形式,经统计检验表明,该数学模型预测数据与实验数据吻合,模型方程估计的参数值均具高显著性,表明了该数学模型的精确性.该系统实现了在线色谱分析,操作简便迅速,可用于气固反应动力学的研究. |
| 关 键 词： | 动力学 无梯度 乙醇 脱水 在线色谱分析 |
Experimental Study on the Internal Recycle Gradientless Reactor Used for the Kinetics of Gas-Solid Reaction |
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| GUO Yan-hong,DING Yong-chao,GAO Cai-hong.Experimental Study on the Internal Recycle Gradientless Reactor Used for the Kinetics of Gas-Solid Reaction[J].Chemistry & Bioengineering,2009,26(3). | |
| Authors: | GUO Yan-hong DING Yong-chao GAO Cai-hong |
| Affiliation: | GUO Yan-hong1,DING Yong-chao2,GAO Cai-hong3 |
| Abstract: | A set of internal recycle gradientless reactor system has been designed and assembled for the study of kinetics research.The reliablity of the reactor system is checked by the kinetics of dehydration reaction of ethanol.The mathematical model for dehydration kinetics of ethanol over HZSM-5 zeolite has been established based on experimentally determined data of ethanol dehydration kinetics by using microreactchromatography.It is shown by results from statistic analysis that the predicted parameters by the se... |
| Keywords: | kinetics gradientless ethanol dehydration on-line chromatograph |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
