| Inclusion property and Diels-Alder reaction of bis (diphenylphosphine oxide) butadiyne |
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| 引用本文： | 李明霞,李金亮,王永梅,孟继本. Inclusion property and Diels-Alder reaction of bis (diphenylphosphine oxide) butadiyne[J]. 中国化学, 2000, 18(3): 373-376. DOI: 10.1002/cjoc.20000180321 |
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| 作者姓名： | 李明霞 李金亮 王永梅 孟继本 |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 29572054) and the Natural Science Foundation of Tianjin (No. 963604711). |
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| 摘 要： | The host molecule, bis (diphenylphosphine oxide) butadiyne (2), includes a variety of guests to form five complexes (2a-2e). In addition, the Diels-Alder reaction between 2 and anthracene gives 9, 9', 10, 10'-tetrahedron-9, 9', 10, 10'-bi-ethenoantracene-11, 11'-bis ( diphenylphosphine oxide) (3) which is a potential di-π-methane reactant and can undergo photorearrangement.
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Inclusion property and Diels-Alder reaction of bis (diphenylphosphine oxide) butadiyne |
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| LI,Ming-Xia LI,Jin-Liang WANG,Yong-MeiMENG,Ji-Ben. Inclusion property and Diels-Alder reaction of bis (diphenylphosphine oxide) butadiyne[J]. Chinese Journal of Chemistry, 2000, 18(3): 373-376. DOI: 10.1002/cjoc.20000180321 |
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| Authors: | LI Ming-Xia LI Jin-Liang WANG Yong-MeiMENG Ji-Ben |
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| Affiliation: | LI,Ming-Xia LI,Jin-Liang WANG,Yong-MeiMENG,Ji-BenDepartment of Chemistry,Nankai University,Tianjin 300071,China |
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| Abstract: | The host molecule, bis (diphenylphosphine oxide) butadiyne (2), includes a variety of guests to form five complexes (2a—2e). In addition, the Diels‐Alder reaction between 2 and anthracene gives 9, 9′, 10, 10′‐tetrahedron‐9, 9′, 10, 10′‐bi‐ethenoantracene‐11, 11′‐bis (diphenylphosphine oxide) (3) which is a potential di‐π‐methane reactant and can undergo photorearrangement. |
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| Keywords: | Inclusion Diels-Alder reaction phosphine oxide solid-state reaction |
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