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稀土Eu光转换材料的合成
引用本文:陈士杰.稀土Eu光转换材料的合成[J].山东化工,2009,38(3):15-18.
作者姓名:陈士杰
作者单位:常州刘国钧高等职业技术学校,江苏,常州,213004
摘    要:以聚二甲基硅氧烷(PDMS)为配体,以三苯基氧膦(TPPO)为协同配体,合成稀土铕高分子透明薄膜。用荧光、红外光谱对薄膜进行表征。结果表明薄膜具有良好的荧光性质,并且发现Eu^3+直接键合到PDMS链中的氧原子上。荧光光谱表明配合物同时具有PDMS和Eu^3+的特征发射。

关 键 词:稀土    荧光  配合物

Synthesis of Eu Light-conversion Materials
CHEN Shi-jie.Synthesis of Eu Light-conversion Materials[J].Shandong Chemical Industry,2009,38(3):15-18.
Authors:CHEN Shi-jie
Affiliation:Changzhou Liu Guojun Vocational Technology College;Changzhou 213004;China
Abstract:Rare earth macromolecule transparent films were synthesized by using polydimethylsiloxane as ligand,and using tirphenylphosphine oxide as coordination ligand.The films were characterized by fluorescence and IR spectra.The results showed that the transparent films had good fluorescence characteristics.The fluorescence spectroscopy indicated that the complex both had the emission of PDMS and Eu3+.It was found that Eu3+ was directly bonded to oxygen atoms in PDMS.
Keywords:rare earth  europium  fluorescence  complex  
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