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化工型膨胀床合成MTBE的技术
引用本文:张淑蓉,陈伯伦.化工型膨胀床合成MTBE的技术[J].石油炼制与化工,1998,29(7):24-27.
作者姓名:张淑蓉  陈伯伦
作者单位:抚顺石化公司石油二厂,洛阳石化工程公司
摘    要:抚顺石化公司石油二厂20kt/a化工型膨胀床合成MTBE工业装置,采用了抚顺石化公司石油二厂、洛阳石化工程公司和抚顺石油学院联合开发的技术,所用原料是该炼油厂混合C4中的异丁烯和甲醇在树脂催化剂作用下醚化,过程中除生成纯度高的MTBE外,抽余C4中异丁烯、DME、MTBE、甲醇均达到精细化工原料的要求。装置经过几年运转和完善,各项指标均达到或超过设计指标。

关 键 词:化工装置  膨胀床反应器  制备  叔丁基甲基醚

MTBE SYNTHESIS IN CHEMICAL UNIT WITH SWELLING BED REACTOR
Zhang Shurong,Jin Fujiang.MTBE SYNTHESIS IN CHEMICAL UNIT WITH SWELLING BED REACTOR[J].Petroleum Processing and Petrochemicals,1998,29(7):24-27.
Authors:Zhang Shurong  Jin Fujiang
Abstract:A 20 kt/a chemical unit with swelling bed reactor using the technology developed by No. 2 Refinery of Fushun Petrochemical Company, Luoyang Petrochemical Engineering Company and Fushun Petroleum Institute for synthesizing MTBE has been put into production several years. The isobutylene in mixed C 4 feedstock was etherified with methanol on a resin catalyst. Besides the high purity MTBE product, the isobutylene, DME, MTBE and methanol contents in the remaining C 4 fraction can meet the raw material demand of fine chemicals. The operating result showed that all the targets were reached.
Keywords:chemical unit  swelling bed reactor  preparation  MTBE  
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