| Synthesis,Structure and Luminescent Property of a New Cd(Ⅱ) Complex Containing 2-Propyl-imidazole-4,5-dicarboxylate |
| |
| 引用本文： | 刘新芳,王利亚,马录芳,李荣芳.Synthesis,Structure and Luminescent Property of a New Cd(Ⅱ) Complex Containing 2-Propyl-imidazole-4,5-dicarboxylate[J].结构化学,2010,29(2):280-284. |
| |
| 作者姓名： | 刘新芳 王利亚 马录芳 李荣芳 |
| |
| 作者单位： | College;Chemistry;Chemical;Engineering;Luoyang;Normal;University; |
| |
| 基金项目： | supported by the National Natural Science Foundation of China (No 20771054);;the Foundation of Education Committee of Henan Province (2006150017) |
| |
| 摘 要： | A new Cd(Ⅱ) complex(Cd(H2PIDC)2]n) with singly deprotonated 2-propyl-imidazole-4,5-dicarboxylate as bridging ligand was synthesized and characterized by X-ray diffraction method.Crystal data:monoclinic,space group P21/c,with a=8.2547(11),b=10.7071(15),c=13.9131(14),β=126.164(5)o,V=992.8(2)3,C16H18N4O8Cd,Mr=506.74,Z=2,Dc=1.695g/cm3,F(000)=508,μ=1.151 mm-1,R=0.0296 and wR=0.0812 for 1581 observed reflections.Singly deprotonated ligands(H2PIDC-) act as μ3-bridge and join the Cd(Ⅱ) atoms into a 2-D layer structure.The 2-D layers are further linked by intermolecular hydrogen bonds into a 3D network.The luminescent property of the complex was also investigated.
|
| 关 键 词： | CD（Ⅱ）配合物 结构型式 发光性能 二羧酸 合成 咪唑 丙基 物业 |
Synthesis,Structure and Luminescent Property of a New Cd(Ⅱ) Complex Containing 2-Propyl-imidazole-4,5-dicarboxylate |
| |
| LIU Xin-Fang,WANG Li-Ya,MA Lu-Fang,LI Rong-Fang.Synthesis,Structure and Luminescent Property of a New Cd(Ⅱ) Complex Containing 2-Propyl-imidazole-4,5-dicarboxylate[J].Chinese Journal of Structural Chemistry,2010,29(2):280-284. |
| |
| Authors: | LIU Xin-Fang WANG Li-Ya MA Lu-Fang LI Rong-Fang |
| |
| Affiliation: | College of Chemistry and Chemical Engineering,Luoyang Normal University, Luoyang 471022, China |
| |
| Abstract: | A new Cd(Ⅱ) complex (Cd(H_2PIDC)_2]_n) with singly deprotonated 2-propyl-imidazole-4,5- dicarboxylate as bridging ligand was synthesized and characterized by X-ray diffraction method. Crystal data: monoclinic, space group P2_1/c, with a = 8.2547(11), b = 10.7071(15), c=13.9131(14) (A), β = 126.164(5)°, V = 992.8(2) (A)~3, C_(16)H_(18)N_4O_8Cd, M_r= 506.74, Z = 2, D_c = 1.695g/cm~3, F(000) = 508,μ = 1.151 mm~(-1), R= 0.0296 and wR= 0.0812 for 1581 observed reflections.Singly deprotonated ligands (H_2PIDC~-) act as μ3-bridge and join the Cd(Ⅱ) atoms into a 2-D layer structure. The 2-D layers are further linked by intermolecular hydrogen bonds into a 3D network.The luminescent property of the complex was also investigated. |
| |
| Keywords: | 2-propyl-imidazole-4 5-dicarboxylate crystal structure luminescent property |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
