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A study of synthesizing benzaldehydes from propenylbenzenes and cinnamic acid derivatives
Authors:Maw-Ling Wang  Venugopal Rajendran
Affiliation:Department of Environmental Engineering, Hungkuang University, Shalu, Taichung County 43302, Taiwan
Abstract:Propenylbenzenes and cinnamic acid derivatives yield correspondingly substituted benzaldehydes when oxidized by lead-ruthenium pyrochlore oxide in the presence of sodium hydrochlorite as a co-oxidant at pH 11 under heterogeneous conditions. The reaction of terminal and internal aliphatic alkenes under similar conditions affords no aldehydes.
Keywords:Styrene   Cinnamic acid   Benzaldehye   Lead-ruthenate pyrochlore   Sodium hypochlorite   Oxidation
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