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电子束辐照对高密度聚乙烯/炭黑导电复合材料电阻率的影响
引用本文:张剑锋,郑强,曹苏华,益小苏. 电子束辐照对高密度聚乙烯/炭黑导电复合材料电阻率的影响[J]. 材料工程, 1999, 0(2): 12-15,18
作者姓名:张剑锋  郑强  曹苏华  益小苏
作者单位:1. 浙江大学高分子科学与工程学系
2. 浙江大学高分子科学与工程学系;先进复合材料国防重点实验室
摘    要:研究了电子束辐照固态和熔融态高密度聚乙烯/炭黑(HDPE/CB)导电复合材料的电性能随辐照温度和辐照剂量的变化。结果表明,对固态或熔融态辐照材料而言,其电阻率均随温度的升而而增大。等剂量下,固态辐照材料的PTC强度比熔嘈态辐照的要高,两各状态经高剂量辐后其材料NTC效应消失,,DSC测试证明电阻率的2与基体的结晶行为以及交联链的形成密切相关。

关 键 词:高密度聚乙烯/炭黑导电复合材料  电阻率  电子束辐照  交联

Influence of Electron Beam Irradiation on Resitivity of High Density Polyethylene/Carbon Black Conductive Composites
Zhang Jianfeng,Zheng Qiang,Cao Suhua,Yi Xiaosu. Influence of Electron Beam Irradiation on Resitivity of High Density Polyethylene/Carbon Black Conductive Composites[J]. Journal of Materials Engineering, 1999, 0(2): 12-15,18
Authors:Zhang Jianfeng  Zheng Qiang  Cao Suhua  Yi Xiaosu
Abstract:Influence of electron beam irradiation on the resitivity of carbon black loaded high density polyethylene(HDPE/CB) conductive composites were studied The results showed that resitivity increased with increasing temperature The PTC intensity of composites irradiated at room temperature was higher than that irradiated at melting temperature under the same irradiation dose For two different irradiation conditions, NTC effect disappeared when irradiation doses were over 200kGy The changes of resitivity were related to crystallinity and crosslinking of polyethylene by irradiation
Keywords:high density polyethylene/ carbon black conductive composites resitivity electron beam irradiation crosslinking
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