| 2,9,16,23-四联苯基金属酞菁的合成、溶解性及光学性质 |
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| 引用本文： | 张欣,王军,赵宝中,付强,白建伟,杨彬.2,9,16,23-四联苯基金属酞菁的合成、溶解性及光学性质[J].分子科学学报,2006,22(3):159-164. |
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| 作者姓名： | 张欣 王军 赵宝中 付强 白建伟 杨彬 |
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| 作者单位： | 1. 东北师范大学化学学院,吉林,长春,130024;大庆师范学院化学学院,黑龙江,大庆,163712
2. 东北师范大学化学学院,吉林,长春,130024 |
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| 摘 要： | 合成了2,9,16,23-四联苯基金属(Fe,Co,Ni,Cu和Zn)酞菁。研究了合成产物的质谱、溶解性、紫外光谱以及荧光光谱．结果表明,取代基使金属酞菁的溶解性增加,不发生二聚,紫外光谱发生红移。
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| 关 键 词： | 联苯基 锌酞菁 溶解性 荧光 |
| 文章编号： | 1000-9035(2006)03-0159-06 |
| 收稿时间： | 11 3 2004 12:00AM |
| 修稿时间： | 2004年11月3日 |
Synthesis, dissolvability and optical properties of 2,9,16,23-Four Biphenyl metal phthalocyanines |
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| ZHANG Xin,WANG Jun,ZHAO Bao-zhong,FU Qiang,BAI Jian-wei,YANG Bin.Synthesis, dissolvability and optical properties of 2,9,16,23-Four Biphenyl metal phthalocyanines[J].Journal of Molecular Science,2006,22(3):159-164. |
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| Authors: | ZHANG Xin WANG Jun ZHAO Bao-zhong FU Qiang BAI Jian-wei YANG Bin |
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| Affiliation: | 1. Chemistry Department, Northeast Normal University, Changehun, 130024; 2. Chemistry Department, Daqing Normal College, Daqing, 163712 |
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| Abstract: | 2,9,16,23-four-biphenyl metal phthalocyanines were prepared The compounds were studied on mass spectrum, dissolvability, UV spectrum and fluorescence. The results show that substituent on phthalocyanines result in the increase of solubility and hindering the dimerization as well as the red shif for UV of synthesized compounds. |
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| Keywords: | biphenyl substituent metal phthalocyanine dissolvability fluorescence |
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